Fluorine is the most electronegative element, meaning it has the greatest attraction for electrons. This is because fluorine has the highest ionization energy and electron affinity of all the elements. In other words, it takes more energy to remove an electron from fluorine than any other element, and fluorine has the strongest attraction for electrons of any other element.
When fluorine is combined with sulfur, the fluorine atoms will attract the electrons in the sulfur-fluorine bond more strongly than the sulfur atoms. This will cause the sulfur atoms to have a positive charge and the fluorine atoms to have a negative charge.