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  • Calculating pH of a Buffer Solution: Henderson-Hasselbalch Equation
    To determine the approximate pH of the solution, we can use the Henderson-Hasselbalch equation:

    pH = pKa + log([A-]/[HA])

    where:

    pH is the pH of the solution

    pKa is the acid dissociation constant of the conjugate acid (trimethylammonium ion)

    [A-] is the concentration of the base (trimethylamine)

    [HA] is the concentration of the conjugate acid (trimethylammonium chloride)

    Given that the concentration of trimethylamine ([A-]) is 0.04 M and the concentration of trimethylammonium chloride ([HA]) is 0.2 M, we can substitute these values into the Henderson-Hasselbalch equation:

    pH = pKa + log([A-]/[HA])

    pH = 9.8 + log(0.04/0.2)

    pH = 9.8 - 0.7

    pH = 9.1

    Therefore, the approximate pH of the solution is 9.1, which is closest to option 1 (9.2).

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