Protons have a positive charge of +1, while electrons have a negative charge of -1.
Charge of 3 protons = 3 x (+1) = +3
Charge of 2 electrons = 2 x (-1) = -2
Overall charge = Charge of protons + Charge of electrons
= +3 + (-2)
= +1
Therefore, the net charge of 3 protons and 2 electrons is +1.