The permanganate ions are reduced by the water molecules to form manganese dioxide (MnO2) and oxygen (O2). The manganese dioxide is a brown solid that precipitates out of the solution. The oxygen gas bubbles out of the solution. The following chemical equation shows the reaction that takes place:
2KMnO4 + H2O → MnO2 + O2 + 2KOH
The reaction between potassium permanganate and water is an example of a redox reaction. A redox reaction is a chemical reaction in which there is a transfer of electrons between two or more species. In the case of the reaction between potassium permanganate and water, the potassium permanganate is reduced and the water is oxidized.