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  • CO2 vs. SO2: Which Lower pH in Water? - Chemistry Explained
    Sulfur dioxide ($SO_2$) lowers the pH of water more than carbon dioxide ($CO_2$) when equal amounts of each are introduced.

    Both $CO_2$ and $SO_2$ react with water to form acids, but $SO_2$ produces a stronger acid.

    $$CO_2(g) + H_2O(l) ⇌ H_2CO_3(aq)$$

    $$H_2CO_3(aq) ⇌ H^+(aq) + HCO_3^-(aq); Ka_1 = 4.5\times10^{-7}$$

    $$SO_2(g) + H_2O(l) \rightarrow H^+(aq) + HSO_3^-(aq)$$

    $$HSO_3^-(aq) \rightarrow H^+(aq) + SO_3^{-2}(aq); Ka_2 = 1.2 \times 10^{-2}$$

    The stronger acidity of sulfurous acid ($H_2SO_3$) compared to carbonic acid ($H_2CO_3$) is due to the higher stability of the sulfate ion ($SO_3^{-2}$).

    Therefore, introducing an equal amount of $SO_2$ into water will result in a lower pH than introducing an equal amount of $CO_2$.

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