There are a few reasons why sodium hydroxide is a stronger base than ammonia:
1. Electronegativity: Sodium is a metal, and ammonia is a nonmetal. Metals are generally less electronegative than nonmetals, meaning that they have a weaker attraction for electrons. This means that the hydroxide ion (OH-) in sodium hydroxide has a stronger attraction for H+ ions than the ammonia molecule (NH3).
2. Solvation: Sodium hydroxide is a highly soluble compound in water, while ammonia is only moderately soluble. This means that there are more OH- ions available in a solution of sodium hydroxide than there are NH3 molecules in a solution of ammonia. The more ions there are in a solution, the more effective the base is at accepting H+ ions.
3. Dissociation: Sodium hydroxide completely dissociates in water, meaning that all of the NaOH molecules break apart into Na+ and OH- ions. Ammonia, on the other hand, only partially dissociates in water, meaning that some of the NH3 molecules remain intact as neutral molecules. The more a compound dissociates in water, the more effective the base is at accepting H+ ions.
As a result of these factors, sodium hydroxide is a stronger base than ammonia. This means that it is more effective at accepting H+ ions and can raise the pH of a solution more effectively.