The reason why sodium loses its outermost electron is because it is not very strongly attracted to the nucleus. This is because the outermost electron is far from the nucleus, and the force of attraction between the nucleus and the electron decreases as the distance between them increases. In addition, the outermost electron is shielded from the nucleus by the other electrons in the atom. This shielding effect also reduces the force of attraction between the nucleus and the outermost electron.
As a result of these factors, sodium's outermost electron is weakly held and can be easily removed from the atom. When sodium loses this electron, it becomes positively charged because it now has one more proton than electron.