In 1911, Ernest Rutherford performed the gold foil experiment. In this experiment, a beam of alpha particles (positively charged helium nuclei) was fired at a thin sheet of gold foil. Most of the alpha particles passed through the foil without any deflection. However, a small number of alpha particles were deflected at large angles or even bounced back.
Rutherford's experiment showed that the positive charge of the atom must be concentrated in a small, dense nucleus. This led to the development of the Rutherford model of the atom, which consists of a small, positively charged nucleus surrounded by negatively charged electrons in fixed circular orbits.