PV = nRT
Where:
P = pressure = 1 atm
V = volume (unknown)
n = number of moles = 1 mole
R = ideal gas constant = 0.08206 L*atm/mol*K
T = temperature = 273.15 K
Solving for V, we get:
V = nRT/P
V = (1 mole) * (0.08206 L*atm/mol*K) * (273.15 K) / (1 atm)
V = 22.414 L
Therefore, the volume of 1 mole of methane gas at STP is 22.414 liters.