Even though a concentrated weak acid has a high concentration of acid molecules, it still has a low dissociation constant. This means that only a small fraction of the acid molecules actually dissociate in water. The majority of the acid molecules remain undissociated, and so the solution has a low pH.
For example, hydrochloric acid (HCl) is a strong acid that completely dissociates in water. This means that all of the HCl molecules in solution dissociate into H+ and Cl- ions. The dissociation constant for HCl is very high, which means that it is a very strong acid.
On the other hand, acetic acid (CH3COOH) is a weak acid that only partially dissociates in water. This means that only a small fraction of the CH3COOH molecules in solution dissociate into H+ and CH3COO- ions. The dissociation constant for acetic acid is very low, which means that it is a very weak acid.
Even though acetic acid is a weak acid, it can still be concentrated. This means that it can have a high concentration of CH3COOH molecules in solution. However, even at high concentrations, acetic acid will still only partially dissociate in water. This means that the solution will have a low pH.