There are a few exceptions to this rule. For example, the solubility of calcium sulfate decreases with increasing temperature. This is because calcium sulfate molecules form strong bonds with water molecules, so the higher the temperature, the more the calcium sulfate molecules dissociate and the less able they are to dissolve in the water.
The table below shows the solubility of a few common solids in water at different temperatures.
| Solid | Solubility at 0°C (g/100g H2O) | Solubility at 100°C (g/100g H2O) |
|---|---|---|
| NaCl | 35.7 | 39.8 |
| CaSO4 | 2.06 | 0.228 |
| NaNO3 | 88 | 187 |