Here's why:
* DNA (Deoxyribonucleic Acid): The "deoxy" in its name refers to the fact that it uses deoxyribose as its sugar. Deoxyribose has one less oxygen atom than ribose.
* RNA (Ribonucleic Acid): RNA uses ribose as its sugar.
The difference in the sugars is one of the key distinctions between DNA and RNA.