Here are some constellations close to Scorpius, both in the sky and in terms of proximity in the celestial sphere:

Directly Adjacent:

* Libra: The Scales, located to the north-west of Scorpius.

* Sagittarius: The Archer, located to the east of Scorpius.

* Lupus: The Wolf, located to the west of Scorpius.

Nearby:

* Ophiuchus: The Serpent Bearer, located to the north of Scorpius.

* Corona Australis: The Southern Crown, located to the west of Scorpius.

* Ara: The Altar, located to the east of Scorpius.

* Norma: The Level, located to the east of Scorpius.

* Telescopium: The Telescope, located to the east of Scorpius.

Note: The exact constellations visible near Scorpius will depend on your location and the time of year. Scorpius is a constellation most prominent in the summer months in the Northern Hemisphere.