Here's why:
* Brightness is relative to distance: We perceive the Sun as the brightest because it's the closest star to us.
* Many stars are much brighter: There are countless stars in the universe that are significantly more luminous than our Sun. For example, the star Sirius, the brightest star in our night sky, is about 25 times brighter than our Sun.
So, while the Sun is vital to our existence, it's not the champion of stellar luminosity.